- Sand Gravel & Aggregate, Wynne
- Sandwich Shop Restaurants, Wynne
- Satellite Dish Antennas & Equipment Dealers, Wynne
- Satellite TV Service, Wynne
- Schools For The Physically Challenged, Wynne
- Scrap & Waste Machinery, Wynne
- Scrap & Waste Materials, Wynne
- Seafood Restaurants, Wynne
- Secondary Schools, Wynne
- Security Brokers & Dealers, Wynne
- Seeds & Bulbs Wholesale & Growers, Wynne
- Senior Citizens Service & Health Organizations, Wynne
- Sewer & Drain Cleaning & Repair, Wynne - Drain Cleaner & Installation Services
- Sheriff's Department, Wynne
- Shoe Store - More, Wynne
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- Shoe Stores, Wynne - Mens, Womens & Kids Shoes
- Shopping & Shopping Services, Wynne
- Signs, Wynne
- Social Services & Welfare, Wynne
- Societies & Foundation Associations, Wynne
- Special Education & Care, Wynne
- Specialty Animal Services, Wynne
- Specialty Stores, Wynne
- Sporting Goods Stores, Wynne
- Sportswear Clothing Stores, Wynne - Sports Clothes
- State Government, Wynne
- State Parks, Wynne
- Stocks & Bond Brokers, Wynne
- Stoves & Furnace Equipment, Wynne - Fittings & Repair Parts
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